Chemia Analityczna Volume 46, Number 5 
(September - October 2001)


Inverse Gas Chromatography Study of Acid-Base Properties of Cation Resins Used as Catalysts of Bisphenol A Synthesis

by Marietta Bialon1, Jacek Hetper1, Maciej Kiedik2 and Joanna Glenc1

1University of Opole, Institute of Chemistry, 48 Oleska Street, 45-052 Opole, Poland
2Institute of Heavy Organic Synthesis "Blachownia", 47-225 Kedzierzyn-Kozle, Poland
 

Key words:  inverse gas chromatography, cation resin, ionite, Bisphenol A, acid-base interactions, catalysis

The inverse gas chromatography method have been used for estimation of relative number of acid and base active centres for two type cation exchangers that are used as catalysts of Bisphenol A industrial synthesis. It was stated that after a few weeks of the continuous work of reactors filled with the catalysts, the acid-base properties of the latter have undergone significant changes. The number of acid centres decreased while the number of base centres increased. Simultaneously, the decreased of the yield of the synthesis product was observed.



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