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Faculty of Chemistry
 Pasteura 1, 02-093 Warsaw, Poland   tel.: (+48-22) 5526212
Faculty of Chemistry
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Research Groups
Head of Laboratory: Karol JACKOWSKI
Staff at Professors Positions: Prof. Dr. hab. Karol JACKOWSKI
Staff with Ph.D. Degree: Dr. Włodzimierz MAKULSKI
Dr. Marcin WILCZEK
Ph.D. Students: M.Sc. Piotr GARBACZ
M.Sc. Łukasz JAREMKO

Scientific Activity:

  • Experimental studies of NMR spectral parameters in the gas phase.
  • Intermolecular effects in chemical shifts and spin-spin coupling constants.
  • Measurements of NMR spectral parameters for isolated molecules.
  • Investigation of isotopic effects.
  • Determination of nuclear magnetic dipole moments from NMR spectra.
  • Direct measurements of nuclear magnetic shielding in molecules.
  • Our experiments are performed on NMR spectrometers with superconducting magnets (Varian UNITYplus-200 and INOVA-500) which permit the observation of almost 100 magnetic nuclei; chemicals enriched in selected isotopes are frequently used in our research work.

Representative publications:

  • Antusek A., Jackowski K., Jaszuński M., Makulski W., Wilczek M., "Nuclear magnetic dipole moments from NMR spectra", Chem. Phys. Letters, 411, 111-116 (2005).
  • Maciąga E., Makulski W., Jackowski K., Blicharska B., "Multinuclear NMR studies of gaseous and liquid sevoflurane", J. Mol. Struct. 785, 139-142 (2006).
  • Jackowski K., "Multinuclear NMR spectroscopy in the gas phase", J. Mol. Struct. 786, 215-219 (2006).
  • Jackowski K., Wilczek M., "An experimental test for the approximation of NMR solvent effects by continuum models. 19F gas-to-solution shifts of SF6 and CF4", Polish J. Chem. 80, 1169-1175 (2006).
  • Makulski W., Jackowski K., Antusek A., Jaszuński M., "Gas-phase NMR measurements, absolute shielding scales and magnetic dipole moments of 29Si and 73Ge nuclei", J. Phys. Chem. A, 110, 11462-11466 (2006).
  • Jackowski K., Kubiszewski M., Wilczek M., "13C and 1H nuclear magnetic shielding and spin-spin coupling constants of 13C-enriched bromomethane in the gas phase", Chem. Phys. Letters 440, 176-179 (2007).
  • Jackowski K., Jaszuński M., "Nuclear magnetic moments from NMR spectra - experimental gas phase studies and nuclear shielding calculations", Concepts Magn. Reson. A, 30A, 246-260 (2007).
  • Jackowski K., Jaszuński M., Kamieński B., Wilczek M., "NMR frequency and magnetic dipole moment of 3He nucleus", J. Magn. Reson., 193, 147-149 (2008).
  • Antusek A., Kędziera D., Jackowski K., Jaszuński M., Makulski W., "Indirect spin-spin coupling constants in CH4, SiH4 and GeH4 - Gas-phase NMR experiment and ab initio calculations", Chem. Phys. 352, 320-326 (2008).
  • Jackowski K., Makulski W., Szyprowska A., Antusek A., Jaszuński M., Jusélius J., "NMR shielding constants in BF3 and magnetic dipole moments of 11B and 10B nuclei", J. Chem. Phys. 130, 044309-5 (2009).
  • Jackowski K., Makulski W., Szyprowska A., Antusek A., Jaszuński M., "Temperature dependence of the 1J(11B19F) spin-spin coupling in BF3 molecule", Magn. Reson. Chem. 47, 857-861 (2009).
  • Jackowski K., Jaszuński M., Wilczek M., "Alternative approach to the standardization of NMR spectra. Direct measurements of nuclear magnetic shielding in molecules", J. Phys. Chem. A, 114, 2471-2475 (2010).
  • Jackowski K., Makulski W., "13C shielding scale for MAS NMR spectroscopy" Magn. Reson. Chem. 49, 600-602 (2011).
  • Makulski W., Szyprowska A., Jackowski K., "Precise determination of the 13C nuclear magnetic moment from 13C, 3He and 1H NMR measurements in the gas phase" Chem. Phys. Letters 511, 224-228 (2011).
  • Garbacz P., Piszczatowski K., Jackowski K., Moszyński R., Jaszuński M., "Weak intermolecular interactions in gas-phase nuclear magnetic resonance", J. Chem. Phys. 135, 084310, pp.1-8 (2011).
  • Lantto P., Jackowski K., Makulski W., Olejniczak M., Jaszuński M., "NMR shielding constants in PH3, absolute shielding scale and the nuclear magnetic moment of 31P", J. Phys. Chem. A, 115, 10617-10623 (2011).

Last updated: February 2012