Third Microsymposium of the "International Scholarship Program for Graduate Studies in Faculty of Chemistry, University of Warsaw - From simple molecules to nanostructured and bioactive materials"
October 6 - 8th, 2011, Palace in Łochów, Poland
 
Chronicle
Friday Oct. 7th

15:30 - 16:00 - Sebastian Wojtysiak

Silver-platinum core-shell nanoparticles
for surface-enhanced Raman spectroscopy


Using silver (I) nitrate (V), trisodium citrate and/or sodium borohydride (in systematically changed ratios) various samples of silver nanoparticles in water sol were synthesised. Some of those samples were chosen (after characterisation and SERS measurements) to serve as "seeds" in seed-growth synthesis of Ag@Pt core-shell nanoparticles. Both Ag and Ag@Pt nanoparticles were characterised by microscopic and spectroscopic methods (TEM, UV-Vis, SERS).

Average SERS enhancement factor on Ag@Pt was comparable with best up to now results for platinum.
Modification of Pt layer visible from spectroscopic results (5 cm-1 shift of adsorbed pyrydine oscillation band) justified further electrochemical research for possible electrocatalytic applications.







Discussion





















Stronę oprac. Adam Myśliński