|
Marek Orlik Ph.D., D.Sc. Professor of
Chemistry |
Official address: Laboratory of Electroanalytical Chemistry and Electrocatalysis Faculty of Chemistry The University of Warsaw ul.
Pasteura 1, PL-02-093 Warsaw POLAND |
Contacts |
· Office: Room 356, Division of Inorganic and Analytical Chemistry |
· Tel.: +48 (22) 55 26345 |
· Email: morlik@chem.uw.edu.pl |
· Website: http://beta.chem.uw.edu.pl/people/MOrlik/ |
Academic
education, degrees and positions in Poland |
|
1977 – 1982 |
Studies of chemistry at the University of Warsaw,
Poland. Specialization:
fundamental and applied chemistry. |
1982 |
Magister (M.Sc.) diploma in
chemistry, with distinction for outstanding results. Subject of M.Sc. thesis:
"Mechanisms of Electrode Reactions of Cyanide Complexes of Nickel at Mercury Electrodes". Supervisor: Prof. dr hab. Zbigniew Galus |
1982 – 1990 |
Junior-assistant,
assistant, assistant-lecturer at the Faculty of Chemistry, University
of Warsaw |
1990 – 2004 |
Adiunkt (lecturer)
at the Faculty of Chemistry, University of Warsaw |
1990 |
Doctorate in Chemistry (Ph. D.)
at the Faculty of Chemistry, University of
Warsaw. Subject of Ph.D.
thesis: "Mechanisms of Electrode
Reactions of Cyanide Complexes of Selected Transition Metals at Mercury
Electrodes". Supervisor: Prof. dr hab. Zbigniew Galus. Thesis rewarded by
the Minister of National Education in Poland. |
2000 |
Habilitation at the University of
Warsaw, Faculty of Chemistry. Subject of habilitation thesis: „Experimental and model studies of the electrohydrodynamic convection and chronoamperometric
oscillations as the examples of
self-organization in electrochemical systems“. |
2004 -2020 |
Position of the
extraordinary professor at the Faculty of Chemistry, University of Warsaw |
2010 |
Titular (full) Professor of Chemistry |
2020 – |
Status
of the Ordinary Professor at the University of Warsaw |
http://www.springer.com/9783642276729 http://www.springer.com/9783642276262 |
Scientific stays
outside Poland |
|
1993: |
summer-term stay
at the Johannes Kepler Universität Linz, Austria. Studies on the
kinetics of fast electrode reactions with fast-scan cyclic voltammetry at
ultramicroelectrodes, coulometry; studies on the thermodynamical
transfer properties of cations from water to non-aqueous solvents. Scientific host: Prof. dr. Gerhard Gritzner, Institut für Chemische Technologie Anorganischer Stoffe, Johannes Kepler Universität Linz, A-4040 Linz, Austria. |
1994, 1995 |
summer- and winter
short-term stays at the Johannes Kepler Universität Linz, Austria.
Studies on the kinetics of fast electrode reactions with fast-scan cyclic
voltammetry at ultramicroelectrodes, ac polarography. Numerical
simulation of electrode processes. Scientific host: Prof. dr. Gerhard Gritzner, Institut für Chemische Technologie Anorganischer Stoffe, Johannes Kepler Universität Linz, A-4040 Linz, Austria. |
1996 – 1998 |
Two-year-long
scholarship granted by the Alexander von Humboldt Foundation at the Fritz-Haber-Institut der Max-Planck-Gesellschaft in Berlin, Germany. Subject:
Experimental and theoretical studies of self-organized electrohydro- dynamic convective
patterns in thin-layer electrolytic cells, visualized by
electrochemiluminescence. Scientific mentor:
Dr. habil. Karl Doblhofer |
1999 2000 2002 |
Summer terms:
studies on kinetics of electrode processes in non-aqueous media, using
cyclic voltammetry and chronocoulometry. Computer simulation of
electrochemical processes. Scientific host: Prof. dr. Gerhard Gritzner, Institut für Chemische Technologie Anorganischer Stoffe, Johannes Kepler Universität Linz, A-4040 Linz, Austria. |
April – May 2007 |
Lecturer at the University of
Linz. 1-semester lecture “New
Developments in Electrochemistry” for PhD students |
Current scientific
interests |
Physical and inorganic chemistry:
experiments and numerical modeling. Nonlinear dynamics (oscillations, multistability,
chemical waves) in chemical and electrochemical systems. |
Actual research
projects |
Pattern formation
in chemical systems. Experimental and theoretical studies of oscillations and chemical waves
in chemical reactions involving hydrogen peroxide. Dynamic
instabilities in selected electrochemical processes. |
Past teaching
activity |
Seminars in general chemistry, laboratory courses in: general chemistry, instrumental analysis,
specialization in electrochemistry (numerical modeling of electrode
processes), classes in computer
programming, classes in chemical
calculations in general and analytical chemistry |
Current teaching
activity: lectures |
1. General
Chemistry
2. Inorganic
Chemistry I/II
3. Fundamentals
of Chemical Kinetics with Elements of Nonlinear Dynamics |
HONORS |
|
1. STATE DECORATIONS |
|
1998 |
Medal
of the National Commision of Education -
from the Minister of National Education of
the Republic of Poland |
2009 |
The Silver Cross of Merit - from the President of the Republic of Poland |
2014 |
Gold Medal for Long Service – from the President of the Republic of
Poland |
2018 |
The Gold Cross of Merit – from the President
of the Republic of Poland |
2. SCIENTIFIC
AWARDS |
|
1989 |
Joint award for studies on the mechanisms of electrochemical processes of cyanide complexes of nickel and other transition metals |
1991 |
Award from the Minister of National
Education for the Ph.D. thesis |
1997 |
Professor
Wiktor Kemula Award for the book: „Oscillating
reactions – order and chaos“, founded by the University of Warsaw |
2002 |
Award for the series of publications devoted to self-organisation in electrochemical processes,
founded by the University of Warsaw |
3. AWARDS FOR THE TEACHING ACTIVITY |
|
1982 1983 1984 1998 1992 1993 |
individual and joint awards from the Rector of the University of Warsaw and from the Faculty of Chemistry for the educational achievements |
2004 |
Joint Award from the Minister
of National Education for the
contribution to the development of the Chemistry Olympiad |
2004 |
Professor Arkadiusz Piekara Award for the excellence in teaching, founded by University of Warsaw |
2014 |
Title of the „Academic Teacher of the Year in the Field of Exact Science“, awarded by the Students‘ Government of the University of Warsaw |
2016 |
Award of the first degree for the excellence in teaching, from the Rector of the University of Warsaw |
2020 |
Jan Harabaszewski medal for outstanding achievements in the field of teaching chemistry, awarded by The Polish Chemical Society |
|
|
2016 |
Bicentennary Medal of the University of Warsaw, awarded by the Rector |
Membership of
professional societies and organizational activity |
|
1978 - |
Member of the Polish Chemical
Society (PTChem) |
2008 - 2020 |
Member of American Chemical
Society (ACS) |
2009 - |
Member of the International
Society of Electrochemistry (ISE) |
1981 - |
Member of the Polish Main Committee of Chemistry Olympiad |
Sept 1, 2005 – Aug 31, 2014 |
Vice-President of the Polish Main Committee of Chemistry Olympiad |
Sept 1, 2014 - |
President of the Polish Main Committee of Chemistry Olympiad |
1986 - 1996, 1998 – 2004 |
Subeditor of the Polish Journal
"Chemistry in School" |
2005 - |
Editor-in-chief of the Polish Journal "Chemistry in School" |
SELECTED
PUBLICATIONS |
A. BOOKS |
1. Marek
Orlik: Self-Organization in
Electrochemical Systems. I. General Principles
of Self-Organization. Temporal Instabilities. In: Scholz F.
(ed.) Monographs in Electrochemistry, Springer, Berlin-Heidelberg
2012, ISBN
978-3-642-27672-9 , 528 pp |
2. Marek Orlik: Self-Organization in Electrochemical
Systems. II.
Spatiotemporal Patterns and Control of Chaos. In: Scholz F.
(ed.) Monographs in Electrochemistry, Springer, Berlin-Heidelberg 2012, ISBN
978-3-642-27626-2, 448 pp |
3. Marek Orlik: Oscillating
Reactions. Order and Chaos. WNT, Warsaw 1996, ISBN
83-204-1970-0, 360 pp (in Polish) |
4. W. Danikiewicz, M.
Orlik, R. Retelewski, E. Migdal (Ed.): Collection
of CompetitionTasks from National Chemistry Olympiads XXVIII-XXX. WSiP, Warsaw 1987, ISBN 83-02-03112-7, 305 pp (in Polish) |
5. M. Orlik, M.
Jelińska-Kazimierczuk (Eds.): Collection of Competition
Tasks from National Chemistry Olympiads L-LIX., Wyd.
Naukowe PWN SA, Warsaw 2014, ISBN 978-83-01-17831-4, 672 pp (in Polish) |
B. REVIEW CHAPTERS IN BOOKS |
1.
M. Orlik, Z. Galus: “Electrochemistry of Gold”, 2. M. Orlik, Z. Galus: “Electrochemistry
of Silver” 3. M. Orlik, Z. Galus, “Electrochemistry of Mercury” in “Encyclopedia of Electrochemistry” (Ed.
A. J. Bard, M. Stratmann), vol. 7 „Inorganic Chemistry”, (Ed. F. Scholz, C.
J. Pickett), WILEY-VCH, 2006),
pp. 839 – 991. 4. M.
Orlik: “Silver” In “Encyclopedia of Electrochemical Power Sources”, Elsevier 2023, w druku |
C. SELECTED ORIGINAL
SCIENTIFIC PUBLICATIONS |
M. Orlik Digital simulation of cyclic voltammetry
in a two-electrode system and its application to the kinetics of
bis(biphenyl) chromium(I) in N,N-dimethylformamide J. Electroanal.
Chem., 1997, 434, 139 – 152 |
M. Orlik, J. Rosenmund, K. Doblhofer, G. Ertl, Electrochemical formation of luminescent convective patterns in
thin-layer cells J. Phys. Chem. B, 1998, 102, 1397 –
1403 |
M. Orlik, K. Doblhofer, G. Ertl, On the mechanism of electrohydrodynamic convection in the thin-layer
electrolytic cells J.
Phys. Chem. B, 1998, 102, 6367
– 6364 |
M. Orlik On
the onset of the self-organizing
electrohydrodynamic convection in thin-layer
electrolytic cells J. Phys. Chem. B, 1999, 103, 6629 – 6642 |
M. Orlik On the geometrical shape of
self-organizing electrohydrodynamic convective flows generated in thin‑layer
electrolytic cells Phys. Chem. Chem. Phys. 1999, 1 , 5359 - 5367 |
R. Jurczakowski, M. Orlik The oscillatory
course of the electroreduction of thiocyanate complexes of nickel(II) at
mercury electrodes - experiment and simulation J.
Electroanal. Chem., 2000, 486,
65 - 74 |
M. Orlik On the
self-organization of the convective motion of fluid, driven by electric
forces in the thin-layer electrolytic cells Electrochem. Commun., 2000, 2,
522 – 526 |
R. Jurczakowski, M. Orlik Bistable/oscillatory
system based on the electroreduction of thiocyanate complexes of nickel(II)
at a streaming mercury electrode J. Phys. Chem. B, 2002, 106, 1058 – 1065 |
M. Orlik, R. Jurczakowski On the stability of nonequilibrium steady-states for the electrode
processes at a streaming mercury electrode J. Phys.
Chem. B, 2002, 106,
7527 – 7536 |
M. Łobacz, M. Orlik, J. Stroka, Z. Galus: Method of separation and determination of the characteristics of the adsorbed and nonadsorbed states of electroactive substances on electrodes Langmuir, 2002, 18,
2765 – 2770 |
R. Jurczakowski, M. Orlik,
Ni(II)-N3- complexes at a streaming mercury
electrode J. Phys. Chem. B, 2003, 107, 10148 – 10158 |
R. Jurczakowski, M. Orlik The apparent faradaic response in the impedance characteristics
of the capacitive current at a streaming mercury electrode J. Electroanal. Chem., 2004, 562, 205 – 215 |
L. Kišová, J. Komenda, I. Mayr, M. Orlik and G. Gritzner: Electrode kinetics of Eu3+ in sodium perchlorate solutions
in dimethylsulfoxide J. Electroanal. Chem., 2004, 565, 367 – 373 |
M. Orlik, G. Gritzner Chronocoulometric
studies of the kinetics of the electroreduction of Eu3+ in dimethylsulfoxide – experiment and simulations J. Electroanal. Chem., 582 (2005) 144 – 150 |
J. S. Jaworski, M. Cembor, M. Orlik, Anisole as a solvent for organic
electrochemistry J. Electroanal.
Chem., 582 (2005) 165 – 170 |
R. Jurczakowski, M. Orlik: Experimental
and theoretical impedance studies of oscillations and bistability
in the Ni(II)-SCN- electroreduction at the streaming mercury
electrode, J. Electroanal.
Chem., 605 (2007) 41 - 52 |
K. Pękala, R. Jurczakowski, A. Lewera, M. Orlik:
Luminescent chemical waves in the Cu(II)-catalyzed
oscillatory oxidation of SCN- ions
with hydrogen
peroxide
J. Phys. Chem. A, 111 (2007) 3439 -
3442 |
M. Orlik, R. Jurczakowski: The kinetic parameters of the
electrocatalytic reduction of the coordinated azide
anions found from comparison of dc and ac
measurements for the tristable Ni(II)-N3-
system J. Electroanal. Chem., 614 (2008) 139 – 148 |
M. T. Gorzkowski,
R. Jurczakowski, M. Orlik:
Electrochemical oscillations and bistability
in the redox processes of mercury ions, coupled with the self-induced convection
of Hg surface J. Electroanal. Chem., 615 (2008) 135 – 144 |
M. Orlik, M. T. Gorzkowski: The simple model and linear stability analysis of the electrode
process with the NDR region caused by the
potential-dependent convective transport J. Electroanal. Chem., 617 (2008)
64 – 70 |
A. Wiśniewski, W. K. Czerwiński,
P. Paklepa, P. K. Wrona,
M. Orlik: The convection-driven
non-additivity of the faradaic currents fort the parallel reduction of some metal and hydrogen cations at the mercury electrode J. Electroanal. Chem., 623 (2008)
120 – 128 |
K. Pękala, R. Jurczakowski, M.
Orlik: On the interpretation of the potentiometric response of the
inert solid electrodes in the
monitoring of the oscillatory processes involving hydrogen peroxide J. Solid State Electrochem., 14 (2010)
27-34 |
A. Wiśniewski, K. Pękala, M. Orlik: Kinetic model of the H2O2 – SCN- - OH-
- Cu2+ oscillator and its
application to the interpretation of the potentiometric responses of various inert
electrodes monitoring the reaction course J. Phys. Chem. A, 114 (2010) 183-190 |
K. Pękala, A. Wiśniewski, R. Jurczakowski,
T. Wiśniewski, M. Wojdyga, M. Orlik: Monitoring of spatiotemporal patterns in the oscillatory chemical
reactions with the infrared camera: experiments and model interpretation J. Phys. Chem. A, 114 (2010) 7903-7911 |
M. T. Gorzkowski, A. Wesołowska, R. Jurczakowski, P. Ślepski, K. Darowicki, M. Orlik: Electrochemical oscillations and bistability
during anodic dissolution of vanadium electrode in acidic media – part I. Experiment J. Solid State Electrochem. 15 (2011)
2311-2320 |
M. T. Gorzkowski, M. Orlik: Electrochemical oscillations and bistability
during anodic dissolution of vanadium electrode in acidic media – part II. The model J. Solid State Electrochem. 15 (2011)
2321-2330 |
A. Wiśniewski, M. T. Gorzkowski, K. Pekala, M. Orlik: Thermokinetic origin of luminescent travelling fronts in the H2O2-NaOH-SCN-
- Cu2+ homogeneous oscillator: experiments and model J. Phys. Chem. A, 117 (2013) 11155 - 11166 |
A. Wiśniewski, M. Jędrusiak,
I. Mojzych, M. Orlik: Model calculations and experimental studies as a route toward simplification
of the kinetic mechanism of the H2O2-NaSCN-NaOH-CuSO4
homogeneous oscillator Int. J. Chem. Kinet., 47 (2015) 671 – 683 |
M. Jędrusiak, A. Wiśniewski,
M. Orlik: The model of “minimal oscillator” derived from the kinetic mechanism
of the H2O2-NaSCN-NaOH-CuSO4
dynamical system Int. J. Chem. Kinet., 47 (2015) 791 - 802 |
M. Jędrusiak, M. Orlik: The formation and spatiotemporal progress of the pH
wave induced by the temperature gradient in the thin-layer H2O2 – Na2S2O3
– H2SO4 - CuSO4 dynamical system J. Phys. Chem. B, 120 (2016) 3169-3177 |
M. Jędrusiak, G. Matyszczak, M. Orlik: On the phase shifts in the dynamics of the H2O2-Na2S2O3-H2SO4-CuSO4
oscillator revealed by comparison of potentiometric
responses of different indicator electrodes Int. J. Chem. Kin. 49 (2017) 250-258 |
Ž. D. Cupić, A. F. Taylor, D. Horváth, M. Orlik, I. R. Epstein: Editorial: Advances
in Oscillating Reactions. Front. Chem. 9:690699
(2021) |
P. Oliwa, M. Orlik: Oscillatory chemical reaction as a sensor of Cu(II)-EDTA complex
formation and ligand degradation in copper ion-catalyzed oxidation of thiocyanate
ions with hydrogen peroxide Int. J. Chem. Kin. 53 (2021) 1314 – 1329; https://doi.org/10.1002/kin.21535 |
D. Selected
other scientific reviews in journals |
1. M. Orlik: The Fluid Convection as the Self-Organised Phenomenon in Electrochemical Systems. in: "Recent Research Developments in Physical Chemistry.”, S. G. Pandalai (Ed.), Transworld Research Network,
Kerala, India, vol. 6 (2002), s. 495-525
|
2. M. Orlik: Self-organisation
in nonlinear dynamical systems and its relation to the materials science J. Solid State Electrochem., 2009, 13, 245 – 261 |
3. R.
Jurczakowski, M. Orlik: Electrochemical oscillations
and multistability in
the electrode processes of pseudohalogenide
complexes of nickel. Current Topics in Electrochemistry, Research Trends, India, 2007, 12, 51 – 70 |
4. M. Orlik:
Homogeneous redox kinetics vs. interfacial electrochemistry: interpretation
of the
potentiometric characteristics
of some oscillatory chemical reactions in terms of
mixed electrode
potential. Trends in Physical Chemistry, 2018, 18,
15-31 |
5. M. Orlik: The role of temperature in chemical and electrochemical instabilities. Trends
in Physical Chemistry, 2020, 20,
113 – 126 |
6. M. Pribus,
M. Orlik, I. Valent:
From classical metal-catalyzed homogeneous oscillators to an uncatalyzed version of the
Belousov-Zhabootinsky reaction:
a review. Reaction Kinetics,
Mechanisms and Catalysis,
2022, 135, 1211 – 1260 |
E. Published
LECTURE texts |
M.
Orlik: Introduction to the dynamic self-organization
of chemical systems. Part I: Basic concepts and techniques of nonlinear dynamics in chemistry
ChemTexts (2017) 3: 12. https://doi.org/10.1007/s40828-017-0049-5 |
M.
Orlik: Introduction to the
dynamic self-organization of chemical systems. Part II:
Dynamic instabilities in selected
chemical systems ChemTexts (2017) 3: 11. https://doi.org/10.1007/s40828-017-0050-z |
M. Orlik: O siłach napędowych w przyrodzie –
koncepcje, interpretacje, nieporozumienia Wiadomości Chemiczne (2023) 77 (1 -2)
1-34; https://ptchem.pl/storage/pages/January2023/Orlik.pdf |
M. Orlik: Nowoczesne spojrzenie
na konfiguracje elektronowe i układ okresowy pierwiastków, czyli o efektach
relatywistycznych w chemii Wiadomości Chemiczne
(2023) 77 (9-10) 833 - 871 https://ptchem.pl/storage/pages/September2023/Orlik.pdf |